$26M grant fuels UH research on climate-friendly cooling

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A team from the University of Hawaiʻi at Mānoa is tackling an important cause of human-made climate change-common refrigerants used for everything from cooling homes and businesses to freezing and preserving food and medicine. The National Science Foundation (NSF) announced on August 21 that UH and five other universities have been awarded $26 million to establish a fourth generation (Gen-4) NSF Engineering Research Center (ERC) to create sustainable refrigerant technology.

The majority of refrigerants, called hydrofluorocarbons (HFCs), are used in heating, ventilation, air conditioning and refrigeration (HVACR) systems. HVACR systems account for almost 10% of global greenhouse-gas emissions because of leaks that release HFCs into the atmosphere and the significant amount of energy it takes to operate them.

The new NSF Gen-4 ERC Environmentally Applied Refrigerant Technology Hub (EARTH) aims to create a transformative "sustainable refrigerant lifecycle" by lowering HFC emissions; creating safe, property-balanced replacement refrigerants; and increasing the energy efficiency of HVACR systems.

"Understanding the underlying chemistry of new refrigerants in the atmosphere is central to defining the impact onto our climate and ultimately the rise of sea levels," said UH Mānoa Professor Ralf I. Kaiser (Department of Chemistry, College of Natural Sciences), the UH project lead. "We will be developing a tightly integrated collaborative network to predict for the first time the atmospheric impact of potential new refrigerants before they are incorporated into HVACR systems. This is just one aspect of UHʻs role in this important project."

Gen-4 NSF Engineering Research Center

Along with UH, ERC EARTH includes teams from University of Notre Dame, Lehigh University, University of South Dakota, University of Maryland and project lead University of Kansas. The group was selected from among hundreds of other proposed centers following a highly competitive two-year review process. NSF currently supports just 15 ERCs in advanced manufacturing, energy and environment, health and infrastructure.

"For UH to be part of a team selected for a NSF Engineering Research Center just speaks volumes to the quality of our researchers and personnel," said UH Mānoa Provost Michael Bruno. "I cannot overstate its significance, and this groundbreaking project positions UH at the forefront of climate change mitigation while addressing a critical challenge to Hawaiʻi and the world."

NSF Director Sethuraman Panchanathan said ERCs ask big questions in order to catalyze solutions with far reaching impacts.

"NSF Engineering Research Centers are powerhouses of discovery and innovation, bringing America's great engineering minds to bear on our toughest challenges," said Panchanathan. "By collaborating with industry and training the workforce of the future, ERCs create an innovation ecosystem that can accelerate engineering innovations, producing tremendous economic and societal benefits for the nation."

UHʻs many project responsibilities

The UH Mānoa team includes Professors Kaiser, Rui Sun (Department of Chemistry, College of Natural Sciences), Christina Karamperidou (Department of Atmospheric Sciences, School of Ocean and Earth Science and Technology), Kieko Matteson (Department of History, College of Arts, Languages & Letters) and Jennifer Pagala Barnett (Division Of Student Success Student, Diversity and Inclusion). Kaiser says it is fitting that UH is playing such an important role in the project.

"Hawaiʻi is increasingly vulnerable to global warming and its impacts, including more frequent and severe weather extremes and sea level rise," Kaiser said. "Sea level rise, which exacerbates flooding, coastal inundation and erosion, poses a serious threat not only to Hawaiʻi, but also to major population centers along the Pacific Rim, such as Japan and Australia."

Kaiser and Sun's groups will study the atmospheric chemistry of gas phase refrigerants and their interaction with atmospheric ice particles. Kaiser's group will employ crossed molecular beams and acoustic levitators to study the fate of refrigerants in the atmosphere. The efforts are complimented by Sun's computer simulations with artificial intelligence to understand the reaction at the atomistic detail.

"By following this approach, we will avoid the mistakes done in the 1970s, when chlorofluorocarbons (CFCs), an otherwise excellent refrigerant, resulted in catastrophic ozone depletion," Sun said.

Karamperidou, a co-leader of the ERC's research thrust on novel and safe refrigerants, will integrate the experimental and computational data into climate models to study the impacts of HFCs, their replacement compounds, and novel cooling technologies and practices on climate and atmospheric circulation.

"As temperatures continue to rise and with them the frequency and intensity of heat waves, so does the need for refrigeration and air conditioning," said Karamperidou. "This leads to increased refrigerant use and related greenhouse gas emissions, and a vicious cycle between HVACR and global warming that needs to be better understood and ultimately broken."

Matteson will place the modern demand for cooling and its social, environmental, and economic impacts into historical context. She notes that air conditioning technology was first developed in the early twentieth century and didn't become widespread in U.S. homes until the 1970s.

"Now, extreme heat is affecting our health, learning and productivity, and exacerbating disparities between the haves and have-nots," said Matteson. "Mitigating HFCs' harmful effects while ensuring that everyone can function at a livable temperature is a vital social justice issue that needs to be driven by historical understanding as much as science."

As part of the center, UH Mānoa will also establish a new interdisciplinary graduate program in atmospheric chemistry (College of Natural Sciences and SOEST) to train future leaders in chemistry, atmospheric science and environmental science.

Diversity and Culture of Inclusion

Barnett will manage the Diversity and Culture of Inclusion (DCI) for the ERC, spearheading initiatives to support and advance EARTH's diversity goals for students, faculty and staff. A major focus is to recruit and increase participation of Indigenous and tribal communities.

"I am looking forward to this opportunity to bring our commitment to diversity to our partner universities and to this important effort," said Barnett. "This is a global issue that we are trying to address and one of the keys to success is to ensure that all voices are being considered and heard and offered an equitable opportunity to affect change."

"For our team to be leading the DCI initiatives for the entire ERC shows how UH, and Hawaiʻi in general, lead the nation in these types of efforts," said Bruno. "We are committed to being a Native Hawaiian Place of Learning and fully embracing our multicultural and multi-ethnic communities. This is an opportunity to extend that forward thinking to the continent."

Allen Vincent, a 4th year Chemistry PhD student in Sun's lab, is the President of the Student Leadership Council (SLC) for ERC EARTH. He leads an active council of 26 students from the partner institutions who are all involved in research and academic activities for the ERC. The SLC will work closely with DCI efforts to address the ERC culture, diversity and recruitment of students.

Workforce training

ERC EARTH will work with industry to develop workforce goals that will involve community colleges to address workforce gaps. The UH team will work with the UH community colleges through coordinated outreach and training to prepare the next generation of HVACR workers.

"This project demonstrates the amazing synergies we can achieve when our campuses work together," said UH President David Lassner. "Our world-class researchers will be developing solutions to a major challenge facing the planet with the commitment to train not just the next generation of researchers but also helping our community colleges train local residents for the high-quality jobs that will need to be filled to install and maintain newer systems that are more climate-friendly to our planet."

More about ERC EARTH

The initial $26-million award is eligible for renewal for five additional years until 2034. NSF's ERC program brings technology-based industry and universities together to strengthen the competitive position of American industry in the global marketplace. This ERC has interacting foundational components that go beyond the research project, including engineering workforce development and value creation within an innovation ecosystem that will outlast the lifetime of the ERC.

Link to video and sound (details below): https://spaces.hightail.com/receive/CfXOCUNcrr

VIDEO:

BROLL: (1:24)

0:00-0:25: Hawaiʻi climate broll

0:26-0:55: Broll of air conditioning systems and refrigerators

0:56-1:24: Broll of Prof. Ralf Kaiser's lab

SOUNDBITES:

Ralf I. Kaiser, UH Mānoa chemistry professor and project lead

(0:13)

"The summer is extremely hot. We need air condition systems for people, for cooling systems, for medical reasons. But on the other hand, we have to live in a sustainable world that the chemicals we use don't kill our planet."

Kaiser on the dangers of hydrofluorocarbons, which are currently used in a majority of refrigerants

(0:15)

"They were introduced in the 90s as a replacement for chlorohydrocarbons, which damage the ozone layer. So these new chemicals do not damage the ozone layer, but they have a side effect that contributes significantly to global warming, much more than carbon dioxide.